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Morphology-conserved transformation: synthesis of hierarchical mesoporous nanostructures of Mn(2)O(3) and the nanostructural effects on Li-ion insertion/deinsertion properties

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Morphology-conserved transformation synthesis of hierarchical mesoporous nanostructures of Mn(2)O(3) and the nanostructural effects on Li-ion insertiondeinsertion properties.pdf (592.1Kb)
Date
2011-02-21
Author
Qiu, Yongcai(Hong Kong Univ Sci & Technol)
Xu, Gui-Liang
Yan, Keyou(Hong Kong Univ Sci & Technol)
Sun, Hui( Hong Kong Univ Sci & Technol, Dept Chem)
Xiao, Junwu( Hong Kong Univ Sci & Technol, Dept Chem)
Yang, Shihe(Hong Kong Univ Sci & Technol)
Sun, Shi-Gang
孙世刚
Jin, Limin( S China Normal Univ, Guangdong Higher Educ Inst)
Deng, Hong( S China Normal Univ, Guangdong Higher Educ Inst)
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  • 化学化工-已发表论文 [14469]
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Abstract
By means of morphology-conserved transformation, we have synthesized hierarchically structured Mn(2)O(3) nanomaterials with different morphologies and pore structures. The key step of this method consists of the formation of a precursor containing the target materials interlaced with the judiciously chosen polyol-based organic molecules, which are subsequently knocked out to generate the final nanomaterials. In the present work, two kinds of precursor morphologies, oval-shaped and straw-sheaf-shaped, have been selectively prepared by hydrothermal treatment of different functional polyol molecules (oval-shape with fructose and straw-sheaf-shape with beta-cyclodextrin) and potassium permanganate. Thermal decomposition of the precursors resulted in the formation of mesoporous Mn(2)O(3) maintaining the original morphologies, as revealed by extensive characterization. These novel hierarchical nanostructures with different pore sizes/structures prompted us to examine their potential as anode materials for lithium ion batteries (LIBs). The electrochemical results with reference to LIBs show that both of our mesoporous Mn(2)O(3) nanomaterials deliver high reversible capacities and excellent cycling stabilities at a current density of 200 mA g(-1) compared to the commercial Mn(2)O(3) nanoparticles. Moreover, the straw-sheaf-shaped Mn(2)O(3) exhibits a higher specific capacity and a better cycling performance than the oval-shaped one, due to the relatively higher surface area and the peculiar nanostrip structure resulting in the reduced length for lithium ion diffusion. Morphology-conserved transformation yields two kinds of hierarchical mesoporous Mn(2)O(3) nanomaterials with high capacities and cycling stabilities for lithium ion batteries.
Citation
JOURNAL OF MATERIALS CHEMISTRY,2011,21(17):6346-6353
URI
http://dx.doi.org/doi:10.1039/c1jm00011j
WOS:000289524300034
https://dspace.xmu.edu.cn/handle/2288/11976

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