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A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate

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A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate.pdf (1.009Mb)
Date
2011-07-20
Author
Chen, Li-Juan(Fujian Normal Univ, Coll Chem & Mat)
Su, Jiang-Bo(Fujian Normal Univ, Coll Chem & Mat)
Huang, Rong-Bin
黄荣彬
Lin, Shen(Fujian Normal Univ, Coll Chem & Mat)
Yang, Ming-Xing(Fujian Normal Univ, Coll Chem & Mat)
Huang, Hua(Fujian Normal Univ, Coll Chem & Mat)
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  • 化学化工-已发表论文 [14469]
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Abstract
A 2D tri-layer compound {[Co(8)(tbip)(6)(H(2)O)(9)(OH)(4)]center dot 12(H(2)O)}(n) (1) (H(2)tbip = 5-tert-butyl isophthalic acid) consisting of novel heptacobaltate clusters and single cobalt centers bridged by tbip(2-) ligands has been hydrothermally synthesized. The complex represents a rare example of a homometallic coordination polymer built up from both heptanuclear metal clusters and single metal centers simultaneously. The magnetic investigation reveals that the complex exhibits the overall predominance of antiferromagnetic coupling between magnetic centers.
Citation
DALTON TRANSACTIONS,2011,40(38):9731-9736
URI
http://dx.doi.org/doi:10.1039/c1dt10723b
WOS:000295038400012
https://dspace.xmu.edu.cn/handle/2288/11951

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