dc.contributor.author | Song, Wei-Chao(Nankai Univ, Dept Chem) | |
dc.contributor.author | Tao, Jun | |
dc.contributor.author | 陶军 | |
dc.contributor.author | Hu, Tong-Liang(Nankai Univ, Dept Chem) | |
dc.contributor.author | Zeng, Yong-Fei(Nankai Univ, Dept Chem) | |
dc.contributor.author | Bu, Xian-He(Nankai Univ, Dept Chem) | |
dc.date.accessioned | 2012-04-01T00:09:02Z | |
dc.date.available | 2012-04-01T00:09:02Z | |
dc.date.issued | 2011-10-06 | |
dc.identifier.citation | DALTON TRANSACTIONS,2011,40(44):11955-11959 | zh_CN |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://dx.doi.org/doi:10.1039/c1dt11099c | |
dc.identifier.uri | WOS:000296776200039 | |
dc.identifier.uri | https://dspace.xmu.edu.cn/handle/2288/11948 | |
dc.description.abstract | As a continuation of the study on using the tetrazolate ligands to construct coordination polymers, two isomorphous 3D coordination polymers built on Delta-chain topological rod-shaped SBUs have been synthesized with formulae [M(2)(mu(3)-OH)L(1)L(2)](n) (5-amino-1H-tetrazole (HL(1)), 2,3-pyrazinedicarboxylic acid (H(2)L(2)) and different 3d spin carriers (M = Mn(II), 1 and Co(II), 2)). The SBU consists of corner-sharing [M(3)(mu(3)-OH)] isosceles triangle motifs with mixed multiple (mu(4)-tetrazolyl, mu(3)-OH, syn-syn carboxylate) bridges. The SBUs were further linked by syn-anti carboxylates to form the sra net. Spin-competing was observed in the Mn(II) compound, whereas the Co(II) compound exhibits spin-canting. | zh_CN |
dc.description.sponsorship | 973 Program of China[2007CB815305]; NNSF of China[51073079, 21031002]; Natural Science Fund of Tianjin, China[10JCZDJC22100]; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University | zh_CN |
dc.language.iso | en | zh_CN |
dc.publisher | ROYAL SOC CHEMISTRY | zh_CN |
dc.title | Isomorphous tetrazolate Mn(II) and Co(II) compounds built on Delta-chain showing different magnetic behaviors | zh_CN |
dc.type | Article | zh_CN |