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dc.contributor.authorSong, Wei-Chao(Nankai Univ, Dept Chem)
dc.contributor.authorTao, Jun
dc.contributor.author陶军
dc.contributor.authorHu, Tong-Liang(Nankai Univ, Dept Chem)
dc.contributor.authorZeng, Yong-Fei(Nankai Univ, Dept Chem)
dc.contributor.authorBu, Xian-He(Nankai Univ, Dept Chem)
dc.date.accessioned2012-04-01T00:09:02Z
dc.date.available2012-04-01T00:09:02Z
dc.date.issued2011-10-06
dc.identifier.citationDALTON TRANSACTIONS,2011,40(44):11955-11959zh_CN
dc.identifier.issn1477-9226
dc.identifier.urihttp://dx.doi.org/doi:10.1039/c1dt11099c
dc.identifier.uriWOS:000296776200039
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11948
dc.description.abstractAs a continuation of the study on using the tetrazolate ligands to construct coordination polymers, two isomorphous 3D coordination polymers built on Delta-chain topological rod-shaped SBUs have been synthesized with formulae [M(2)(mu(3)-OH)L(1)L(2)](n) (5-amino-1H-tetrazole (HL(1)), 2,3-pyrazinedicarboxylic acid (H(2)L(2)) and different 3d spin carriers (M = Mn(II), 1 and Co(II), 2)). The SBU consists of corner-sharing [M(3)(mu(3)-OH)] isosceles triangle motifs with mixed multiple (mu(4)-tetrazolyl, mu(3)-OH, syn-syn carboxylate) bridges. The SBUs were further linked by syn-anti carboxylates to form the sra net. Spin-competing was observed in the Mn(II) compound, whereas the Co(II) compound exhibits spin-canting.zh_CN
dc.description.sponsorship973 Program of China[2007CB815305]; NNSF of China[51073079, 21031002]; Natural Science Fund of Tianjin, China[10JCZDJC22100]; State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen Universityzh_CN
dc.language.isoenzh_CN
dc.publisherROYAL SOC CHEMISTRYzh_CN
dc.titleIsomorphous tetrazolate Mn(II) and Co(II) compounds built on Delta-chain showing different magnetic behaviorszh_CN
dc.typeArticlezh_CN


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