Polyoxometalate-supported ruthenium nanoparticles as bifunctional heterogeneous catalysts for the conversions of cellobiose and cellulose into sorbitol under mild conditions
Date
2011-07-25Author
Liu, Mi
Deng, Weiping
Zhang, Qinghong
张庆红
Wang, Yanliang
Wang, Ye
王野
Collections
- 化学化工-已发表论文 [14469]
Abstract
Ru nanoparticles loaded on a Keggin-type polyoxometalate (Cs(3)PW(12)O(40)), which did not possess strong intrinsic acidity, efficiently catalysed the conversions of cellobiose and cellulose into sorbitol in water medium in H(2) at <= 433 K. The Bronsted acid sites generated in situ from H(2) have been demonstrated to play a key role in the formation of sorbitol.
Citation
CHEMICAL COMMUNICATIONS,2011,47(34):9717-9719URI
http://dx.doi.org/doi:10.1039/c1cc12506kWOS:000293858700047
https://dspace.xmu.edu.cn/handle/2288/11944