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Butylphenyl-functionalized palladium nanoparticles as effective catalysts for the electrooxidation of formic acid

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Butylphenyl-functionalized palladium nanoparticles as effective catalysts for the electrooxidation of formic acid.pdf (1.478Mb)
Date
2011-04-26
Author
Zhou, Zhi-You
周志有
Kang, Xiongwu( Univ Calif Santa Cruz, Dept Chem & Biochem)
Song, Yang( Univ Calif Santa Cruz, Dept Chem & Biochem)
Chen, Shaowei( Univ Calif Santa Cruz, Dept Chem & Biochem)
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  • 化学化工-已发表论文 [14237]
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Abstract
Monodisperse butylphenyl-functionalized palladium (Pd-BP, dia. 2.24 nm) nanoparticles were synthesized through co-reduction of butylphenyldiazonium and H(2)PdCl(4) by NaBH(4). Because of this unique surface functionalization and a high specific electro-chemical surface area (122 m(2) g(-1)), the Pd-BP nanoparticles exhibited a mass activity similar to 4.5 times that of commercial Pd black for HCOOH electrooxidation.
Citation
CHEMICAL COMMUNICATIONS,2011,47(21):6075-6077
URI
http://dx.doi.org/doi:10.1039/c1cc11235j
WOS:000290628000039
https://dspace.xmu.edu.cn/handle/2288/11936

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