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Liquid vertical bar liquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids

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Liquidliquid electrochemical bicarbonate and carbonate capture facilitated by boronic acids.pdf (738.9Kb)
Date
2011-10-03
Author
Collins, Andrew M.(Univ Bath, Dept Chem)
Watkins, John D.(Univ Bath, Dept Chem)
Katif, Najoua(Univ Bath, Dept Chem)
Huang, Yan-Jun
Jiang, Yun-Bao
江云宝
James, Tony D.(Univ Bath, Dept Chem)
Bull, Steven D.(Univ Bath, Dept Chem)
Marken, Frank(Univ Bath, Dept Chem)
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  • 化学化工-已发表论文 [14469]
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Abstract
Reversible bicarbonate and carbonate liquid|liquid ion transfer processes from aqueous solution into an organic 4-(3-phenylpropyl)pyridine phase are driven electrochemically with TPPMn(III/II) and shown to be facilitated over a wide pH range by 2-naphthylboronic acid (bicarbonate transfer potential -0.08 V vs. SCE; binding constant K(AB) = 10 2 mol(-1) dm(3) and carbonate dianion transfer potential 0.07 V vs. SCE; binding constant K(AB2) = 2 x 10(10) mol(-2) dm(6)).
Citation
CHEMICAL COMMUNICATIONS,2011,47(43):12002-12004
URI
http://dx.doi.org/doi:10.1039/c1cc15211d
WOS:000296202800057
https://dspace.xmu.edu.cn/handle/2288/11915

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