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High-resolution 2D NMR spectra in inhomogeneous fields based on intermolecular multiple-quantum coherences with efficient acquisition schemes

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High-resolution 2D NMR spectra in inhomogeneous fields based on intermolecular multiple-quantum coherences with efficient acquisition schemes.htm (394bytes)
Date
2011-10-16
Author
Lin, Meijin( Xiamen Univ, Minist Educ)
Huang, Yuqing
Chen, Xi
陈曦
Cai, Shuhui
Chen, Zhong
陈忠
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  • 化学化工-已发表论文 [14469]
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Abstract
High-resolution 2D NMR spectra in inhomogeneous fields can be achieved by the use of intermolecular multiple-quantum coherences and shearing reconstruction of 3D data. However, the long acquisition time of 3D spectral data is generally unbearable for in vivo applications. To overcome this problem, two pulse sequences dubbed as iDH-COSY and iDH-JRES were proposed in this paper. Although 3D acquisition is still required for the new sequences, the high-resolution 2D spectra can be obtained with a relatively short scanning time utilizing the manipulation of indirect evolution period and sparse sampling. The intermolecular multiple-quantum coherence treatment combined with the raising and lowering operators was applied to derive analytical signal expressions for the new sequences. And the experimental observations agree with the theoretical predictions. Our results show that the new sequences possess bright perspective in the applications on in vivo localized NMR spectroscopy. (C) 2010 Elsevier Inc. All rights reserved.
Citation
JOURNAL OF MAGNETIC RESONANCE,2011,208(1):87-94
URI
http://dx.doi.org/doi:10.1016/j.jmr.2010.10.009
WOS:000286774300011
https://dspace.xmu.edu.cn/handle/2288/11875

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