Concentration effects in solid-state CD spectra of chiral atropisomeric compounds
Li, Hongkun（Zhejiang Univ, Dept Polymer Sci & Engn）
Qin, Anjun（Zhejiang Univ, Dept Polymer Sci & Engn）
Tang, Ben Zhong（Zhejiang Univ, Dept Polymer Sci & Engn）
- 化学化工－已发表论文 
Atropisomerism is one of the basic concepts in stereochemistry. Chiral crystals of stereochemically labile atropisomers that originated from Mirror Symmetry Breaking (MSB) can only be characterized by solid-state chiroptical techniques. Herein, solid-state circular dichroism and UV-Vis spectra of six atropisomeric compounds (most of them were obtained from MSB) have been studied. A concentration effect including a wavelength shift and inverse concentration-dependence has been found and preliminarily explained by the absorption flattening effect, scattering effect and the torsion in the molecular structures.
CitationNEW JOURNAL OF CHEMISTRY，2011,35（9）：1781-1786