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Targeted synthesis of an electroactive organic framework

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Targeted synthesis of an electroactive organic framework.pdf (895.8Kb)
Date
2010-10-05
Author
Ben, Teng(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
Shi, Kang
时康
Cui, Yan(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
Pei, Cuiying(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
Zuo, Yang
Guo, Han(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
Zhang, Daliang(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
Xu, Jun(Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys)
Deng, Feng(Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys)
Tian, Zhongqun
田中群
Qiu, Shilun(Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem)
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  • 化学化工-已发表论文 [14469]
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Abstract
A new strategy for targeted design and synthesis of an electroactive microporous organic molecular sieve (JUC-Z2) is described. Experiment demonstrated that such a targeted synthesis approach to achieve phenyl-phenyl coupling was a controllable process and predominately generated two-dimensional polymer sheets, significantly different from the traditional chemical or electrochemical oxidation methods to prepare conducting polymers. Successive self-assembly leads to a lamellar organic framework comprised of stacked polymer sheets with an hcb topology. JUC-Z2 was found to have a well-defined uniform micropore distribution (similar to 1.2 nm), a large surface area (BET = 2081 m(2) g(-1)) and high physicochemical stability (> 440 degrees C). After doping with I(2), JUC-Z2 exhibits typical p-type semiconductive properties. As the first example of an electroactive organic framework, JUC-Z2 possesses a unique ability of electrochemical ion recognition, arising from the synergistic function of the uniform micropores and the N-atom redox site.
Citation
J. Mater. Chem., 2011, 21(45): 18208-18214
URI
http://dx.doi.org/doi:10.1039/c1jm12545a
WOS:000296735900012
https://dspace.xmu.edu.cn/handle/2288/11818

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