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Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids

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Nickel-Catalyzed Cross-Coupling of Aryl Phosphates with Arylboronic Acids.htm (392bytes)
Date
2011-03-09
Author
Chen, Hu
Huang, Zhongbin
Hu, Xiaoming
Tang, Guo
唐果
Xu, Pengxiang
Zhao, Yufen
赵玉芬
Cheng, Chien-Hong(Natl Tsing Hua Univ, Dept Chem)
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  • 化学化工-已发表论文 [14469]
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Abstract
The Suzuki-Miyaura cross-coupling of aryl phosphates using Ni(PCy(3))(2)Cl(2) as an inexpensive, bench-stable catalyst is described. Broad substrate scope and high efficiency are demonstrated by the syntheses of more than 40 biaryls and by constructing complex organic molecules. The poor reactivity of aryl phosphates relative to aryl halides is successfully employed to construct polyarenes by selective cross-coupling using Pd and Ni catalysts.
Citation
J. Org. Chem., 2011, 76 (7): 2338–2344
URI
http://dx.doi.org/doi:10.1021/jo2000034
WOS:000288692000051
https://dspace.xmu.edu.cn/handle/2288/11723

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