Vanadium-catalyzed enantioselective oxidation of allyl sulfides

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Date
2011-06-12
Author
Zeng, Qingle（ Chengdu Univ Technol, Coll Mat & Chem & Chem Engn）
Gao, Yuxing
Dong, Junyu（ Chengdu Univ Technol, Coll Mat & Chem & Chem Engn）
Weng, Wen（ Zhangzhou Normal Univ, Dept Chem & Environm Sci）
Zhao, Yufen
赵玉芬
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Abstract
The enantioselective oxidation of allyl sulfides with a vanadyl complex of 3,5-diiodosalicylidene tert-leucinol as a catalyst and aqueous hydrogen peroxide as an oxidant afforded chiral allylsulfoxides with high enantioselectivities of up to 97.3% ee and moderate yields. (C) 2011 Elsevier Ltd. All rights reserved.
Citation
TETRAHEDRON-ASYMMETRY，2011,22（7）：717-721
URI
http://dx.doi.org/doi:10.1016/j.tetasy.2011.04.023
WOS:000292679700002
https://dspace.xmu.edu.cn/handle/2288/11708