Two Three-Dimensional 2p-3d-4f Heterometallic Frameworks Featuring a Ln(6)Cu(24)Na(12) Cluster as a Node
Date
2011-04-01Author
Zhuang, Gui-Lin
Chen, Wen-Xian
Zhao, Hai-Xia
Kong, Xiang-Jian
孔祥建
Long, La-Sheng
龙腊生
Huang, Rong-Bin
黄荣彬
Zheng, Lan-Sun
郑兰荪
Collections
- 化学化工-已发表论文 [14469]
Abstract
Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a nanosized Ln(6)Cu(24)Na(12) (Ln = Gd, Dy) cluster as a node have been obtained under microwave irradiation conditions through the reaction of H(2)ANMA (H(2)ANMA = L-alanine-N-monoacetic acid), Cu(NO(3))(2), and Ln(NO(3))(3) (Ln = Gd for 1, Dy for 2) with NaOH in deionized water. Investigations on the magnetic properties show that 1 exhibits ferrimagnetic behavior. The electrical conductivity measurements reveal that 1 behaves as a proton conductor.
Citation
Inorg. Chem., 2011, 50 (9): 3843–3845URI
http://dx.doi.org/doi:10.1021/ic200077rWOS:000289710700001
https://dspace.xmu.edu.cn/handle/2288/11669