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Concise Asymmetric Total Synthesis of 9-epi-Sessilifoliamide J

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Concise Asymmetric Total Synthesis of 9-epi-Sessilifoliamide J.htm (392bytes)
Date
2011-08-31
Author
Tuo, Shi-Chuan
Ye, Jian-Liang
Wang, Ai-E
Huang, Su-Yu
Huang, Pei-Qiang
黄培强
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  • 化学化工-已发表论文 [14469]
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Abstract
A 10-step asymmetric synthesis of 9-epi-sessilifoliamide J (20), together with sessilifoliamide J (6), has been accomplished from the key chiral building block 11 via a threo-selective vinylogous Mannich reaction and a Ley oxidation-SmI(2)-mediated coupling lactoniation. The absolute configuration of the natural sessilifoliamide J was established.
Citation
Org. Lett., 2011, 13 (19): 5270–5273
URI
http://dx.doi.org/doi:10.1021/ol202140y
https://dspace.xmu.edu.cn/handle/2288/11486
WOS:000295313900075

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