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dc.contributor.authorYu, Shen Luan
dc.contributor.authorLi, Yan Yun
dc.contributor.authorDong, Zhen Rong
dc.contributor.authorZhang, Juan Ni
dc.contributor.authorLi, Qi
dc.contributor.authorGao, Jing Xing
dc.contributor.author高景星
dc.date.accessioned2012-02-21T07:35:08Z
dc.date.available2012-02-21T07:35:08Z
dc.date.issued2011-07-29
dc.identifier.citationCHINESE CHEMICAL LETTERS,2011,22(11):1269-1272zh_CN
dc.identifier.issn1001-8417
dc.identifier.urihttp://dx.doi.org/doi:10.1016/j.cclet.2011.05.033
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11473
dc.identifier.uriWOS:000296223400003
dc.description.abstractNovel chiral PN(4)-type multidentate aminophosphine ligands have been successfully synthesized by Schiff-base condensation of bis(o-formylphenyl)phenylphosphane and various chiral amino-sulfonamides. Their structures were fully characterized by IR, EIMS and NMR. The catalytic systems, prepared in situ from the multidentate ligands and iridium(I) complexes, showed high activity in asymmetric transfer hydrogenation of propiophenone in 2-propanol solution, leading to corresponding optical alcohol with up to 75% ee. (C) 2011 Yan Yun Li and Jing Xing Gao. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.zh_CN
dc.description.sponsorshipNatural Science Foundation of China[20423002, 20703034]; Natural Science Foundation of Fujian Province of China[2008J0235]zh_CN
dc.language.isoenzh_CN
dc.publisherELSEVIER SCIENCE INCzh_CN
dc.subjectChiral multidentate aminophosphine ligandzh_CN
dc.subjectIridium complexzh_CN
dc.subjectPropiophenonezh_CN
dc.subjectAsymmetric transfer hydrogenationzh_CN
dc.titleSynthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenationzh_CN
dc.typeArticlezh_CN


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