Show simple item record

dc.contributor.authorSun, Di( Shandong Univ, Sch Chem & Chem Engn)
dc.contributor.authorLiu, Fu-Jing
dc.contributor.authorHuang, Rong-Bin
dc.contributor.author黄荣彬
dc.contributor.authorZheng, Lan-Sun
dc.contributor.author郑兰荪
dc.date.accessioned2012-02-17T07:04:07Z
dc.date.available2012-02-17T07:04:07Z
dc.date.issued2011-09-09
dc.identifier.citationINORGANIC CHEMISTRY,2011,50(24):12393-12395zh_CN
dc.identifier.issn0020-1669
dc.identifier.urihttp://dx.doi.org/doi:10.1021/ic201746q
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11432
dc.identifier.uriWOS:000297782200018
dc.description.abstractA novel anionic heptadecanuclear silver(I) cluster, (NH(4))(17)[(mu(6)-S)@Ag(17)(mba)(16)]center dot 22H(2)O (1; H(2)mba = 2-mercaptobenzoic acid), was obtained by the reaction of equivalent molar silver oxide and 2,2'-dithiodibenzoic acid (H(2)dtba) under ultrasonic conditions at 50 degrees C. Complex 1 is a discrete cluster comprised of unexpected mba ligands on the shell and a mu(6)-S(2-) ion in the core, suggesting the occurrence of in situ S-S and S-C(sp(2)) bond cleavages of the H(2)dtba ligand. This novel cluster displays moderate orange-red emission in the solid state at room temperature.zh_CN
dc.description.sponsorshipNational Natural Science Foundation of China[21021061, 21071118]; MSTC[2007CB815301]; Independent Innovation Foundation of Shandong University[2011GN030]zh_CN
dc.language.isoenzh_CN
dc.publisherAMER CHEMICAL SOCzh_CN
dc.titleAnionic Heptadecanuclear Silver(I) Cluster Constructed from in Situ Generated 2-Mercaptobenzoic Acid and a Sulfide Anionzh_CN
dc.typeArticlezh_CN


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record