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dc.contributor.authorMAO Shao-Yu
dc.contributor.author毛少瑜
dc.contributor.authorLI Man-Rong
dc.contributor.author李满荣
dc.contributor.authorCHEN Hao-Hong
dc.contributor.author陈昊鸿
dc.contributor.authorHUANG Ya-Xi
dc.contributor.author黄雅熙
dc.contributor.authorMI Jin-Xiao
dc.contributor.author宓锦校
dc.contributor.authorZHAO Jing-Tai
dc.contributor.author赵景泰
dc.date.accessioned2011-12-16T01:06:47Z
dc.date.available2011-12-16T01:06:47Z
dc.date.issued2004
dc.identifier.citationCHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(10):1813-1815zh_CN
dc.identifier.issn0251-0790
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11394
dc.description.abstractA new sodium indium phosphate Na6In4[P7O24(OH)(5)] (.) 4H(2)O was synthesized under a mild hydrothermal condition and its structure was determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in a hexagonal system, space group P6(3), with a = 0.950 23(5) nm, b = 0.950 23(5) nm, c = 1.694 2(2) nm, alpha = 90degrees, beta = 90degrees, gamma = 120degrees, V = 1.324 8(2) nm(3), Z = 8, structure refined to R = 0.052 8 and wR = 0.116 5 for 2 134 independent observed reflections. The three-dimensional network structure consists of helical chains formed by apex-sharing polyhedra. The connection of the chains results in 4- and 8-polyhedral rings and cages centered by three indium metal connecting oxygen atoms formed by three 4-rings. The three-connected oxygen atom is firstly observed in indium phosphate systems.zh_CN
dc.language.isozhzh_CN
dc.publisherHIGHER EDUCATION PRESSzh_CN
dc.subjecthydrothermal synthesiszh_CN
dc.subjectindium phosphatezh_CN
dc.subjectcrystal structurezh_CN
dc.titleHydrothermal synthesis and characterizations of Na6In4[P7O24(OH)(5)]center dot 4H(2)Ozh_CN
dc.typeArticlezh_CN


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