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Hydrothermal synthesis and characterizations of Na6In4[P7O24(OH)(5)]center dot 4H(2)O

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Na_6In_4_P_7O_24_OH_5_4H_2O的水热合成与表征.pdf (193.8Kb)
Date
2004
Author
MAO Shao-Yu
毛少瑜
LI Man-Rong
李满荣
CHEN Hao-Hong
陈昊鸿
HUANG Ya-Xi
黄雅熙
MI Jin-Xiao
宓锦校
ZHAO Jing-Tai
赵景泰
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  • 化学化工-已发表论文 [14469]
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Abstract
A new sodium indium phosphate Na6In4[P7O24(OH)(5)] (.) 4H(2)O was synthesized under a mild hydrothermal condition and its structure was determined by means of single-crystal X-ray diffraction methods. The title compound crystallizes in a hexagonal system, space group P6(3), with a = 0.950 23(5) nm, b = 0.950 23(5) nm, c = 1.694 2(2) nm, alpha = 90degrees, beta = 90degrees, gamma = 120degrees, V = 1.324 8(2) nm(3), Z = 8, structure refined to R = 0.052 8 and wR = 0.116 5 for 2 134 independent observed reflections. The three-dimensional network structure consists of helical chains formed by apex-sharing polyhedra. The connection of the chains results in 4- and 8-polyhedral rings and cages centered by three indium metal connecting oxygen atoms formed by three 4-rings. The three-connected oxygen atom is firstly observed in indium phosphate systems.
Citation
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,2004,25(10):1813-1815
URI
https://dspace.xmu.edu.cn/handle/2288/11394

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