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dc.contributor.authorJun Liang
dc.contributor.authorQinghong Zhang
dc.contributor.author张庆红
dc.contributor.authorHongli Wu
dc.contributor.authorGuanyu Meng
dc.contributor.authorQinghu Tang
dc.contributor.authorYe Wang
dc.contributor.author王野
dc.date.accessioned2011-12-13T02:27:35Z
dc.date.available2011-12-13T02:27:35Z
dc.date.issued2004-09
dc.identifier.citationCATALYSIS COMMUNICATIONS,2004,5(11):665-669zh_CN
dc.identifier.issn1566-7367
dc.identifier.urihttp://dx.doi.org/doi:10.1016/j.catcom.2004.08.010
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11380
dc.description.abstractFe2+-exchanged NaY zeolite and Fe2+-containing compounds including Fe-3(PO4)(2) and Fe3O4 are efficient heterogeneous catalysts for the epoxidation of alkenes with molecular oxygen in the absence of a sacrificial reductant. Fe2+ cations existing in the supercages of zeolite Y or on the surface of the Fe2+-containing compounds probably function as the active sites for the epoxidation with O-2. The solvent plays a crucial role in the epoxidation, and the reactions catalyzed by these iron-based catalysts may proceed via a radical mechanism. (C) 2004 Elsevier B.V. All rights reserved.zh_CN
dc.language.isoenzh_CN
dc.publisherELSEVIER SCIENCE BVzh_CN
dc.subjectepoxidationzh_CN
dc.subjectmolecular oxygenzh_CN
dc.subjectiron-based heterogeneous catalystszh_CN
dc.titleIron-based heterogeneous catalysts for epoxidation of alkenes using molecular oxygenzh_CN
dc.typeArticlezh_CN


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