Synthesis and CD spectra of chiral molybdenum-fullerenyl complexes with pineno-bipyridine ligands
Cai Fei ZHU
Yong Qing HUANG
Jing Xing GAO
- 化学化工－已发表论文 
The synthesis and characterization of two chiral fullerene complexes (+)(430)(CD)- [Mo(eta(2)-C-60) (CO)(3)(L-RR)] 1and (-) CD430CD-[Mo(eta(2)-C-60)(CO)(3)(L-SS)] 2 were described. The CD spectra of 1 and 2 in the visible range show weak Cotton effects, which are approximately of mirror image, indicating that the appended pineno-groups with opposite chirality in bipyridines can perturb the fullerene chromophores through the molybdenum centers and lead to induced CD effects.