Show simple item record

dc.contributor.authorWu Zhenyi
dc.contributor.author吴振奕
dc.contributor.authorYang Sengen
dc.contributor.author杨森根
dc.contributor.authorLin Yongsheng
dc.contributor.author林永生
dc.contributor.authorLiu Jianyong
dc.contributor.author刘见永
dc.contributor.authorTian Ling
dc.contributor.author田玲
dc.contributor.authorPang Zhaoyong
dc.contributor.author庞照勇
dc.contributor.authorCheng Dadian
dc.contributor.author程大典
dc.contributor.authorZhan Mengxiong
dc.contributor.author詹梦熊
dc.date.accessioned2011-12-07T00:21:13Z
dc.date.available2011-12-07T00:21:13Z
dc.date.issued2004
dc.identifier.citationCHINESE JOURNAL OF CHEMICAL PHYSICS,2004,17(6):741-746zh_CN
dc.identifier.issn1003-7713
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11340
dc.description.abstractFulerene complexe C-60 Pd (Ph2PCH2PPh2) was perpared by the method of ligand substitution via the reaction of C-60 with Pd(Ph2PCH2PPh2)(2) under condition of a nitrogen atmosphere and refluxing, and the title compound was appraised and characterized by methods of elemental analysis, FT-IR, UV-vis, XPS and XRD. The results showed that the structure of purposeful product was that the Ph2PCH2PPh2 took up two coordination sites of the central metal, and C-60 took up another two sites in sigma-pi feeback pattern. The porperties on photoelectricity, redox and thermostability of the tide complexe were studied. The results of studying on photoclectricity showed that the photovoltaic effect of (n + n) heterojunction electrode formed by C60Pd(Ph2PCH2PPh2)/GaAs was supper, especially in the BQ/H(2)Q redox couple, and the greatest value of photovoltaic potential was up to 174 mV. The photovoltaic performance of C60Pd (Ph2PCH2PPh2)/GaAs electrode at 1 mum for thickness of C60Pd(Ph2PCH2PPh2) film was the best.zh_CN
dc.language.isozhzh_CN
dc.publisherSCIENCE CHINA PRESSzh_CN
dc.subjectfullerenezh_CN
dc.subjectpalladium complexezh_CN
dc.subjectphotovoltaic effectzh_CN
dc.titleSynthesis and photovoltaic effect study for fullerene complexe C60Pd(Ph2PCH2PPh2)zh_CN
dc.typeArticlezh_CN


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record