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Studies on the diastereoselective reductive alkylation of (R)-phenylglycinol derived phthalimide: observation of stereoelectronic effects

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Studies on the diastereoselective reductive alkylation of (R)-phenylglycinol derived phthalimide observation of stereoelectronic effects.htm (413bytes)
Date
2004-12
Author
Ming-De Chen
Ming-Zhu He
Xiang Zhou
Li-Qiang Huang
Yuan-Ping Ruan
阮源萍
Pei-Qiang Huang
黄培强
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  • 化学化工-已发表论文 [14469]
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Abstract
Full details of a flexible approach to N-protected (R)-3-alkyl-isoindolin-1-ones 13 via diastereoselective reductive-alkylation are described, with emphasis on the stereochemical outcome of the key diastereoselective reactions. Additional experiments allowed finding remarkable stereoelectronic effects on the reductive ring-opening reactions. (C) 2004 Elsevier Ltd. All rights reserved.
Citation
TETRAHEDRON,2005,61(50:1335-1344
URI
http://dx.doi.org/doi:10.1016/j.tet.2004.10.109
https://dspace.xmu.edu.cn/handle/2288/11272

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