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dc.contributor.authorHU, Sheng-Zhi
dc.contributor.author胡盛志
dc.contributor.authorCHEN, Ming-Dan
dc.contributor.author陈明旦
dc.contributor.authorROBERTSON
dc.date.accessioned2011-11-14T14:54:20Z
dc.date.available2011-11-14T14:54:20Z
dc.date.issued2005
dc.identifier.citationACTA PHYSICO-CHIMICA SINICA,2005,21(6):646-652zh_CN
dc.identifier.issn1000-6818
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/11183
dc.description.abstractThirty coordination polyhedra, reflecting the presence of a stereoactive lone electron pair, in the crystal structures of antimony (II) aminopolycarboxylic complexonates reported in the literature, have been revised. The presence of the lone pair has been acknowledged by including secondary bonded ligand atom (s) in the vicinity of the lone pair of each antimony(III). The resulted polyhedra are discussed in terms of their dihedral angles. In order to focus on the inherent coordination geometry of the central Sb(III) the vertices of the overall polyhedron are moved to the surface of a unit sphere. Inclusion of secondary bonding ligand atom(s) is supported by the valence bond calculations.zh_CN
dc.language.isozhzh_CN
dc.publisherPEKING UNIV PRESSzh_CN
dc.subjectcoordination polyhedronzh_CN
dc.subjectsecondary bondingzh_CN
dc.subjectbond valence sumzh_CN
dc.subjectantimony(III) complexzh_CN
dc.subjectaminopolycarboxylic acidzh_CN
dc.subjectVSEPR theoryzh_CN
dc.titleStudy on the scondary bonding and coordination polyhedra in crystal of antimony(III) complexonate familyzh_CN
dc.typeArticlezh_CN


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