Synthesis and characterization of novel covalently linked - Fullerene-porphyrin compouds
- 化学化工－已发表论文 
In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand (H2P-C-60) was synthesized by 1, 3-dipolar cycloaddition reaction of C-60, sarcosine and H2P-CHO, and it's zinc derivative was prepared by metalation of H2P-C-60 and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and H-1 NMR. They are also predicted to have good optical and electrical properties.