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dc.contributor.authorLinyan
dc.contributor.author林珩
dc.contributor.authorChenguoliang
dc.contributor.author陈国良
dc.contributor.authorZhengzishan
dc.contributor.author郑子山
dc.contributor.authorZhoujianzhang
dc.contributor.author周建章
dc.contributor.authorChenshengpei
dc.contributor.author陈声培
dc.contributor.authorLinzhonghua
dc.contributor.author林仲华
dc.date.accessioned2011-10-18T14:51:30Z
dc.date.available2011-10-18T14:51:30Z
dc.date.issued2005
dc.identifier.citationACTA PHYSICO-CHIMICA SINICA,2005,21(11):1280-1284zh_CN
dc.identifier.issn1000-6818
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/10943
dc.description.abstractThe adsorption and oxidation of isopropanol in alkaline media at platinum electrode have been investigated by using electrochemical quartz crystal microbalance (EQCM) and in situ FTIR spectroscopy. The results show that there is no self-poisoning in the electrooxidation of isopropanol in alkaline media. Though no poison species, such as CO, are evidenced by in situ FTIR spectroscopy, the adsorption of isopropanol or its dissociative products on Pt surface is suggested by EQCM data. The final product of isopropanol oxidation is only acetone under experimental condition, which suggests that the oxidation of isopropanol into acetone takes place via dehydrogenation step. The EQCM studies provide quantitative results of surface mass variation and have thrown new light in the elucidating isopropanol oxidation.zh_CN
dc.language.isoenzh_CN
dc.publisherPEKING UNIV PRESSzh_CN
dc.subjectPt electrodezh_CN
dc.subjectelectrooxidationzh_CN
dc.subjectisopropanolzh_CN
dc.subjectin situ FTIRzh_CN
dc.subjectEQCMzh_CN
dc.subjectalkaline mediazh_CN
dc.titleThe adsorption and oxidation of isopropanol at platinum electrode in alkaline mediazh_CN
dc.typeArticlezh_CN


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