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A perchlorate-promoted electrochemically induced nitride coupling reaction

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A perchlorate-promoted electrochemically induced nitride coupling reaction.htm (413bytes)
Date
2005-10
Author
Pak-Ho Chan
Sheng-Pei Chen
陈声培
Kin-Wai Yeung
Kwong-Chak Cheung
Shuangjin Hong
Shi-Gang Sun
孙世刚
Kwok-Yin Wong
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  • 化学化工-已发表论文 [14469]
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Abstract
The osmium nitride complex [Os-VI(NH3)(4)N](3+) undergoes a one-electron reduction in acetonitrile to give [Os-V(N)(NH3)(4)](2+), which further reacts by nitride coupling to give the p-dinitrogen osmium complex [(CH3CN)(NH3)(4)Os-II(N-2)Os-II(NH3)(4)(CH3CN)](4+). The formation of the p-dinitrogen osmium complex is promoted by the presence of perchlorate anion, which causes the deposition of [(CH3CN)(NH3)(4)Os-II(N-2)Os-II(NH3)(4)(CH3CN)](ClO4)(4) On the electrode surface upon repetitive voltammetric scans. (c) 2005 Elsevier B.V. All rights reserved.
Citation
ELECTROCHEMISTRY COMMUNICATIONS,2005,7(12):1244-1248
URI
http://dx.doi.org/doi:10.1016/j.elecom.2005.08.028
https://dspace.xmu.edu.cn/handle/2288/10929

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