Molten salt route toward the growth of ZnO nanowires in unusual growth directions
Date
2005-11Author
Zhi-Yuan Jiang
江智渊
Tao Xu
Zhao-Xiong Xie
谢兆雄
Zhi-Wei Lin
Xi Zhou
Xin Xu
徐昕
Rong-Bin Huang
黄荣彬
Lan-Sun Zheng
郑兰荪
Collections
- 化学化工-已发表论文 [14469]
Abstract
ZnO nanowires with unusual growth directions, such as the approximate < 102 > and the < 100 > directions, were prepared by using the LiCl molten salt synthetic method. Intrinsic crystallographic structures and the growth directions of the as-prepared ZnO nanowires were investigated by using selected area electron diffraction and high-resolution transmission electron microscopy. In the present case, Li+ and Cl- ions of molten salts may bind with O2- and Zn2+ ions, respectively, of the {101} and {001} polar surfaces of the ZnO crystals, resulting in the decrease of their surface energies and tuning the growth directions by blocking the growth on the polar surfaces. A combination of the growth along the < 102 >, < 100 >, and < 210 > directions may lead to the formation of complex tree like ZnO dendrites. Strong green light emission was observed from room-temperature PL spectra of the as-prepared ZnO nanowires. This molten-salt synthetic process could be extended to synthesize other kinds of unusual 1D nanomaterials with specific crystal structures and properties.