Synthesis and photoelectric property for the fullerene complex C60Pd(Ph2PCH2CH2CH2CH2PPh2)
- 化学化工－已发表论文 
Fullerene complexe C60Pd(Ph2PCH2CH2CH2CH2PPh2) was prepared by replacement reaction in inert atmosphere and characterized by elemental analysis, IR, electronic spectroscopy, XPS and XRD. At the same time, the properties on redox and thermostability of the product were studied. The photoltaic effect of C60Pd (Ph2PCH2CH2CH2CH2PPh2) complex on GaAs electrode formation n+n heterojunction in photoelectrochemical cell H H I was investigated. The results show that the photoelectric property of CPd(Ph2PCH2C2CH2C2PPh2) is excellent, especially in the BQ/H(2)Q redox couple mediator. The photovoltaic property of C60Pd(Ph2PCH2CH2CH2PPh2)GaAs electrode at 1 mu m for thickness of C60Pd(Ph2PCH2CH2CH2CH2PPh2) is the best, the photopotential value is up to 212 mV.