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脉冲梯度场增强的DQF-COSY实验t_1噪声研究(英文)
P TYPE GRADIENT ENHANCED DQF COSY EXPERIMENTS SHOW LOWER t 1 NOISE THAN N TYPE *

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脉冲梯度场增强的DQF-COSY实验t_1噪声研究(....pdf (241.4Kb)
Date
1999
Author
林国兴
廖新丽
林东海
郑绍宽
陈忠
吴钦义
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  • 化学化工-已发表论文 [14235]
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Abstract
脉冲相位的不稳定性是导致二维谱中的T1噪声的原因之一.本文从理论上和实验上对脉冲相位不稳定性所引起的T1噪声进行了研究.从角动量算符IX,Iy和Iz推导中发现,由于磁化矢量在P型和n型dQfCOSy实验的脉冲梯度场中进动方向的内在差异,一部分脉冲相位误差在P型dQfCOSy实验会被重聚掉,在n型dQfCOSy实验中却会被加重.因此P型dQfCOSy实验的T1噪声比n型小.理论推导还得到T1噪声在P型和n型中的理论比值为3∶11.以上理论结果得到我们实验结果的支持
 
t 1 noise, stemming from the instabilities of pulse phases in 2D spectroscopy, has been investigated theoretically as well as experimentally.Based on the angular momentum operator I x,I y,I z formalism, our deductions show that the different precessing directions of the magnetization between P type and N type gradient enhanced DQF COSY experiments result in that P type gradient enhanced DQF COSY experiments refocus the phase errors of pulses, while N type gradient enhanced DQF COSY experiments strengthen the effect of the phase errors of pulses.Therefore, t 1 noise in P type gradient enhanced DQF COSY experiments is lower than that in N type.In addition, the theoretical ratio of P type to N type is 3∶11, which is supported by our experimental results.
 
Citation
波谱学杂志,1999,(1):13-20
URI
https://dspace.xmu.edu.cn/handle/2288/107719

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