η--2-C_(60)[RhCl(CO)(PPh_3)_2]配合物的合成与表征

Abstract

从1985年SMAlEy等［1］发现C60等富勒烯至1996年富勒烯的发现者获诺贝尔化学奖期间，在化学、材料、物理等领域形成了富勒烯的研究热潮［2~5］.现在科学工作者正以较大的注意力投向富勒烯的化学修饰，研究富勒烯各类衍生物的结构与性能之间内在联系...

The fullerene complex, 2C602], has been prepared by the reaction of C60 with RhCl(CO)(PPh3)2 in benzene at room temperature.The new complex was characterized by elemental analysis, IR, XPS and electronic spectra.The result show that the complex of 2 form can be formed by C60 bonding to RhCl(CO)(PPh3)2 in the way. In addition, the complex structure has been supposed.