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铁(III)催化砜基α-碳负离子偶联成烯的非异构化证据
Evidence for Absence of Isomerization of Double Bond During Iron (III) catalyzed Sulfone α Carbanion Homocoupling

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铁(III)催化砜基α-碳负离子偶联成烯的非异构化证....pdf (91.28Kb)
Date
1998
Author
靳立人
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  • 化学化工-已发表论文 [14469]
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Abstract
以β,β-二氘代砜为反应物进行铁(II)催化的砜基α-碳负离子的去砜基偶联烯烃化反应,用1HnMr测定生成的氘代烯烃直接证明该反应体系中未发生双键迁移.
 
By using β,β dideuterosulfone as starting material, the iron (III) catalyzed α sulfonylcarbanion desulfonitive homocoupling to form the corresponding deuteroalkene was demonstrated to be absence of double bond migration.
 
Citation
厦门大学学报(自然科学版),1998,(5):88-90
URI
https://dspace.xmu.edu.cn/handle/2288/107577

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