Show simple item record

dc.contributor.author许翩翩
dc.contributor.author高景星
dc.contributor.author郑荣辉
dc.contributor.author彭蔚萍
dc.contributor.author黄培强
dc.contributor.author万惠霖
dc.contributor.author王文国
dc.contributor.author丁开宁
dc.contributor.author陈守正
dc.date.accessioned2016-05-17T02:55:38Z
dc.date.available2016-05-17T02:55:38Z
dc.date.issued1998
dc.identifier.citation高等学校化学学报,1998,(3):117-120
dc.identifier.issn0251-0790
dc.identifier.otherGDXH803.026
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/107474
dc.description.abstract利用C2-对称的双胺双膦钌(Ⅱ)配合物ruCl2(P2n2H4)为催化剂,研究了苯乙酮的氢转移还原反应.在苯乙酮、钌配合物和异丙氧基钾的摩尔比为200∶1∶12的条件下,于65℃反应2H后,苯乙酮的转化率高达99%.讨论了苯乙酮的氢转移氢化机理.
dc.description.abstractThe catalytic hydrogen transFer hydrogenation of acetophenone using C 2 symmetric diamine/diphosphine ruthenium(Ⅱ) complex has been studied.Complex RuCl 2(P 2N 2H 4) shows an excellent catalytic activity in hydrogen transFer hydrogenation of acetophenone in a molar ratio of substrate/Ru/ iso PrOK 200∶1∶12, leading to 2 phenylethanol in 99% yield aFter 2 h.A hydrogen transFer mechanism is also discussed.
dc.description.sponsorship国家自然科学基金;中国石油化学工业总公司石油化工科学院资助
dc.language.isozh_CN
dc.subject胺膦钌配合物
dc.subject苯乙酮
dc.subject氢化
dc.subjectAminophosphine ruthenium complex
dc.subjectAcetophenone
dc.subjectHydrogenation
dc.title多齿胺膦钌配合物催化苯乙酮的氢转移氢化
dc.title.alternativeHydrogen TransFer Hydrogenation of Acetophenone by Ruthenium Complexes Containing Polydentate Aminophosphine Ligand
dc.typeArticle


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record