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新的双胺双膦钌配合物的合成、表征和催化性能
Synthesis, Characterization and Catalytic Properties of New Diamino/Diphosphine Ruthenium Complexes

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新的双胺双膦钌配合物的合成、表征和催化性能.pdf (248.9Kb)
Date
1997
Author
许翩翩
高景星
王文国
陈忠
黄培强
万惠霖
蔡启瑞
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  • 化学化工-已发表论文 [14237]
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Abstract
Polydentate ligands, N,N'-bis[o-(diphenylphosphino)benzylidene]-1,2-propane-dia-mine [P2N2Me For short] and N,N'-bis[o-(diphenylphosphino)benzy1]-12-propanediamine [P2N2 H4Me For short] have been synthesized.The interaction of RuCl2(DMSO)4 with one equiv-alent of P2N2Me or P2N2H4Me in reFluxing toluene gave trans-RuCl2(P2N2Me) and trans-RuClz(P2N4H4Me) in good yield, respectively.The ligands and the complexes have been Fully characterized by elemental analysis and spectroscopic methods.The complexes act as an excellent catalyst precursor in hydrogen transFer hydrogenation of aretophenone in catalyst: aretophenone :iso-PrOK of 1: 100: 15, leading to 2-phenylethanol of 89-96% yield.
Citation
物理化学学报,1997,(6):484-488
URI
https://dspace.xmu.edu.cn/handle/2288/107371

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