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dc.contributor.author庞然
dc.contributor.author金曦
dc.contributor.author赵刘斌
dc.contributor.author丁松园
dc.contributor.author吴德印
dc.contributor.author田中群
dc.date.accessioned2016-05-17T02:54:28Z
dc.date.available2016-05-17T02:54:28Z
dc.date.issued2015-11-10
dc.identifier.citation高等学校化学学报,2015,(11):18-29
dc.identifier.issn0251-0790
dc.identifier.otherGDXH201511003
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/107138
dc.description.abstract对于在分子水平上研究电化学表面吸附和反应过程,表面增强拉曼光谱(SErS)显示出了其独到的优势,提供了有力的技术方法,但对于其表面增强机理仍有待深入研究.本文总结了将量子化学计算应用于电化学表面增强拉曼光谱(EC-SErS)分析的研究,以电化学界面分子吸附、电化学反应以及光电化学反应的研究体系为模型,提取EC-SErS光谱所蕴藏的物理化学信息.通过对吡啶在电化学表面的吸附、水的吸附及其电化学反应、以及对巯基苯胺的电化学表面催化偶联反应等体系的研究,揭示了电化学表面吸附、反应和光电化学过程的本质.
dc.description.abstractConsidering the study of electrochemical surface adsorption and reaction processes at the molecular level,Surface-enhanced Raman spectroscopy( SERS) shows its particular merits and provides a powerful technical method for this study.However,the mechanism of enhancement needs to be further explored.This review summarizes the systematic work on electrochemical SERS( EC-SERS) by combining quantum chemistry calculations.On the basis of these studies,we can make deep insight for extracting the physical and chemical information in EC-SERS spectra.Focusing on adsorption of pyridine on the electrochemical surface,adsorption and reactional process of water on the surface,and surface coupling reaction for p-aminothiophenol,we had illustrated the nature of the adsorption and photochemical reactions on the electrochemical surface.
dc.description.sponsorship国家自然科学基金(批准号:21373712;21321062;21533006); 国家重点基础研究项目(批准号:2015CB932303); 厦门大学固体表面物理化学国家重点实验室开放基金(批准号:201416)资助~~
dc.language.isozh_CN
dc.subject量子化学
dc.subject表面增强拉曼光谱
dc.subject电荷转移态
dc.subject表面等离激元共振
dc.subject电化学
dc.subjectQuantum chemistry
dc.subjectSurface-enhanced Raman spectroscopy
dc.subjectCharge transfer state
dc.subjectSurface plasmon resonance
dc.subjectElectrochemistry
dc.title电化学表面增强拉曼光谱的量子化学研究
dc.title.alternativeQuantum Chemistry Study of Electrochemical Surface-enhanced Raman Spectroscopy
dc.typeArticle


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