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dc.contributor.authorQun-Hong Weng
dc.contributor.author翁群红
dc.contributor.authorQiao He
dc.contributor.author何桥
dc.contributor.authorDi Sun
dc.contributor.author孙頔
dc.contributor.authorHui-Ying Huang
dc.contributor.author黄慧英
dc.contributor.authorSu-Yuan Xie
dc.contributor.author谢素原
dc.contributor.authorXin Lu
dc.contributor.author吕鑫
dc.contributor.authorRong-Bin Huang
dc.contributor.author黄荣彬
dc.contributor.authorLan-Sun Zheng
dc.contributor.author郑兰荪
dc.date.accessioned2011-08-26T00:51:43Z
dc.date.available2011-08-26T00:51:43Z
dc.date.issued2011-06-09
dc.identifier.citationJOURNAL OF PHYSICAL CHEMISTRY C,2011,115( 22):11016-11022zh_CN
dc.identifier.issn1932-7447
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/10681
dc.descriptionsyxie@xmu.edu.cn, xinlu@xmu.edu.cnzh_CN
dc.description.abstractAlthough derivatives of fullerenes are prevalent in the fullerene-producing flame, the chemistry of these derivatives has rarely been discussed in the previous literature. In this paper, two D(Sh)-C(70) derivatives, C(70)(C(14)H(10)) and C(70)(C(5)H(6)), were isolated from the soot of an acetylene benzene combustion. On the basis of detailed MS, NMR, IR, and UV/vis analyses in combination with DFT calculations, the cycloadduct structures of C(70)(C(14)H(10)) and C(20)(C(5)H(6)) were identified. Both the anthracene (C(14)H(10)) and the cyclopentadiene (C(5)H(6)) adducts, supposed as the intermediate species produced during the combustion process, were characterized to bond at a [6,6] ring junction at the end of the olivary C(70) cage. The present work exemplifies the capture of possible intermediates by the C(70) fullerene from the flame and thus provides insight into the mechanism responsible for the formation of fullerene-containing soot.zh_CN
dc.description.sponsorshipNSFC 21031004 ,20973137,21021061 973 projects 2007CB815301 ,2007CB815307zh_CN
dc.language.isoenzh_CN
dc.publisherAMER CHEMICAL SOCzh_CN
dc.subjectPOLYCYCLIC AROMATIC-HYDROCARBONSzh_CN
dc.subjectFULLERENIC NANOSTRUCTURESzh_CN
dc.subjectCOMBUSTION SYNTHESISzh_CN
dc.subjectCHEMICAL-SYNTHESISzh_CN
dc.subjectDIFFUSION FLAMEzh_CN
dc.subjectC-60zh_CN
dc.subjectC-70zh_CN
dc.subjectCARBONzh_CN
dc.subjectCHLOROFORMzh_CN
dc.subjectCHEMISTRYzh_CN
dc.titleSeparation and Characterization of C70(C14H10) and C70(C5H6) from an Acetylene–Benzene–Oxygen Flamezh_CN
dc.typeArticlezh_CN


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