新型富勒烯膦金属配合物的合成
Synthesis of A Novel Fullerene-phosphine Metal Complex
Abstract
用配体取代法合成了新型富勒烯膦金属配合物——C60.双(二苯基膦)戊烷合钯[C60Pd(dPPPE),1],其结构经uV-VIS,Ir,XPS及元素分析表征。在1的分子结构中,C60以σ-π配位方式与Pd配位,形成新型的η2-C60双齿膦金属配合物。 A novel fullerene-phosphine metal complex,C60Pd(dpppe)(1),was synthesized by ligand substitution method.The structure was characterized by UV-Vis,IR,XPS and elemental analysis.C60 and Pd formed the η2-C60 metal complex of 1 with σ-π coordination bond.