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dc.contributor.authorLin, Hai‐Bin
dc.contributor.authorChen, Can‐Yu
dc.contributor.authorLiao, Xin‐Li
dc.contributor.authorLin, Tao‐Rao
dc.contributor.authorZhou, Zhao‐Hui
dc.contributor.author周朝晖
dc.date.accessioned2011-08-20T11:21:44Z
dc.date.available2011-08-20T11:21:44Z
dc.date.issued2007-02
dc.identifier.citationSYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY,2007,36(5):411-414zh_CN
dc.identifier.issn1553-3174
dc.identifier.urihttp://dx.doi.org/doi:10.1080/15533170600732601
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/10491
dc.description.abstractInvestigation of the reactions between ethylenediamine tetraacetic acid with molybdate(VI) and tungstate(VI) resulted in the isolations of dimeric complexes Na2K2 [Mo2O6 (Edta)] center dot 10H(2)O (1) and Na-4 [W2O6 (Edta)] center dot 8H(2) O (2) (H(4)Edta=ethylenediamine tetraacetic acid) in a wide range of pH values 5-10. The new tungstate complex is resistant for the reaction of hydrogen peroxide, while the reaction of its molybdate homolog results in the isolation of peroxo tetramolybdate(VI) K-8 [Mo4O12 (O-2 )(2)] (3). The three complexes have been characterized by elemental analyses, IR, NMR and X-ray structural analyses. The anions of the complexes 1 and 2 contain two metal atoms and one Edta ligand. Each metal atom is tridentately coordinated by nitrogen and carboxyl groups of Edta ligand, making metal atom six-coordinate.zh_CN
dc.language.isoenzh_CN
dc.publisherTAYLOR & FRANCIS INCzh_CN
dc.subjectethylenediamine tetraacetic acidzh_CN
dc.subjecttungstatezh_CN
dc.subjectmolybdatezh_CN
dc.subjectcrystal structurezh_CN
dc.titleEthylenediamine tetraacetato trioxomolybdate(VI) and tungstate(VI) and their reactions with hydrogen peroxidezh_CN
dc.typeArticlezh_CN


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