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dc.contributor.authorLin, Ting
dc.contributor.authorLin, Xiang
dc.contributor.authorLu, Chunhua
dc.contributor.authorHu, Zhiyu
dc.contributor.authorHuang, Wenyu
dc.contributor.authorHuang, Yaojian
dc.contributor.authorShen, Yuemao
dc.contributor.author沈月毛
dc.date.accessioned2011-08-08T12:35:39Z
dc.date.available2011-08-08T12:35:39Z
dc.date.issued2009
dc.identifier.citationEUROPEAN JOURNAL OF ORGANIC CHEMISTRY,Volume2009,Issue18,Pages2975-2982,June2009zh_CN
dc.identifier.issn1434-193X
dc.identifier.urihttp://dx.doi.org/doi:10.1002/ejoc.200801021
dc.identifier.urihttps://dspace.xmu.edu.cn/handle/2288/10380
dc.description.abstractEleven new metabolites, including nine lovastatin analogues [oblongolides N-V (1-2 and 5-11), which were defined as naphthalene-type fungal polyketides], one linear furanopolyketide (13) and a monoterpene named dihydroxysabinane (14), together with four known compounds including oblongolides B (3) and C (4), one linear furanopolyketide (12) and the sesterterpene terpestacin (15), were isolated from the endophytic fungal strain Phomopsis sp. XZ-26 of Camptotheca acuminate. Their structures were elucidated by spectroscopic analyses including HR-ESI-MS, H-1 and C-13 NMR, 2D NMR (HMQC, HMBC, H-1-H-1 COSY and NOESY), and X-ray single-crystal analysis. The antimicrobial activities of 1-5, 8, 10 and 13-15 were evaluated, but none showed a substantial effect. Additionally, a hypothetical biosynthetic pathway for oblongolides was proposed. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)zh_CN
dc.description.sponsorshipNational Natural Science Foundation of China [30500632]; National Science Fund for Distinguished Young Scholars [30325044]; Key Grant of Chinese Ministry of Education [306010]zh_CN
dc.language.isoenzh_CN
dc.publisherWILEY-V C H VERLAG GMBHzh_CN
dc.subjectCamptotheca acuminatezh_CN
dc.subjectPhomopsis sp.zh_CN
dc.subjectPolyketideszh_CN
dc.subjectNatural productszh_CN
dc.subjectOblongolidezh_CN
dc.titleSecondary Metabolites of Phomopsis sp XZ-26, an Endophytic Fungus from Camptotheca acuminatezh_CN
dc.typeArticlezh_CN


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