Synthesis and characterization of covalently linked porphyrin-fullerene compounds
- 化学化工－已发表论文 
The covalently linked porphyrin-fullerene dyads were synthesized. The ligand 5-[4-(4"-Phenoxybutoxy) phenyl]-N-(2-methyl)fulleropyrrolidine-10,15,20-tri-(p-methoxyphenyl)porphyrin (H2P-C-60) was synthesized by 1,3 dipolar cycloaddition reaction with C-60, sarcosine and H2P-CHO. The zinc porphyrin-fullerene was prepared by metalation of H2P-C-60 and zinc acetate. The compounds were characterized by meams of IR, UV-Vis, ESI-MS, elemental analysis, and H-1 NMR.