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CeF_3分解制备CeO_2/CeF_3催化剂的丙烷氧化脱氢性能 

贾纬华; 陈明树; 万惠霖 (2014-7-28)
通过分解条件的控制从CEf3制备CEO2/CEf3催化剂.X-射线衍射(Xrd)、rAMAn、低能离子散射谱(lEIS)对制备得到的催化剂进行表征和定量估算,发现CEO2覆盖在CEf3上,随着焙烧温度的升高,CEf3催化剂由外而内分解程度加大.CEf3制备的CEO2/CEf3催化剂的丙烷氧化脱氢(OdHP)性能显著优于CEO2,CEO2覆盖层厚度的增加导致表面f/O摩尔比下降,f-隔离活性位的作用减弱,丙烯选择性由56.3%降低到42. ...

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万惠霖 (1)
贾纬华 (1)陈明树 (1)SubjectCeF3 (1)CeO2 (1)oxidative dehydrogenation (1)
propane (1)
propylene (1)... View MoreDate Issued2014 (1)

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