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Selective modification of surface and bulk V5+/V4+ ratios and its effects on the catalytic performance of Mo-V-Te-O catalysts
(ACADEMIC PRESS INC ELSEVIER SCIENCE, 2007-02)
Selective modification of surface and bulk V5+/V4+ ratios in Mo-V-Te-O catalysts has been achieved using nitric acid and saturated ammonia solutions as pH adjustors. The addition of nitric acid strongly suppressed V4+ in ...
Role of Te on selective oxidation of propane to acrolein over MoBiTeO/SiO2 catalysts
(PEKING UNIV PRESS, 2007)
A series of MoBiTeO/SiO2 catalysts with different Te contents was prepared by impregnation method. Effect of Te on the catalysts'structure, acidity and catalytic performance for selective oxidation of propane to acrolem ...
Studies on VPO/SiO2 catalyst for selective oxidation of propane
(SCIENCE CHINA PRESS, 2003)
VPO catalyst is one of promising catalysts for selective oxidation of C4H10 and C3H8. The catalysts VPO and VPO/SiO2 with different VPO loading were prepared. Using BET, XRD, LRS, XPS, H-2-TPR and C3H8-TPD techniques, the ...
Selective oxidation of propane to acrolein over MoPO/SiO2 catalyst
(SCIENCE CHINA PRESS, 2003)
The selective oxidation of propane to acrolein over the MoPO/SiO2 catalyst has been studied. MoO/SiO2 exhibits only activity for the oxidative dehydrogenation of propane to propene. The propane conversion and acrolein ...
Active surface structure of AgMoO2PO4 center dot MoO3 catalyst for selective oxidation of propane
(HIGHER EDUCATION PRESS, 2001)
The active surface structure of AgMoO2PO4 .MoO3 catalyst was investigated by in situ confocal microprobe Raman spectroscopy, evaluation of catalytic performance, XRD and XPS techniques. The results show that MoO3 and ...
Effect of promoter Ce on silver-molybdenum-phosphate catalysts for selective oxidation of propane to acrolein
(ELSEVIER SCIENCE BV, 2003-02-21)
A series of MenAg0.3Mo0.5P0.3Oy (Me = Cu, Zn, Mn, W, Ce, Pr, Nd) and Ag0.3Mo0.5P0.3Ox catalysts were prepared. The addition of Ce to Ag0.3Mo0.5P0.3Ox catalysts improved the catalytic performance in selective oxidation of ...
Effect of redox properties on selective oxidation of propane to acrolein over molybdate-based catalyst
(SCIENCE CHINA PRESS, 2002)
The Ag-0.3 Mo0.6Ox and Ce0.1Ag0.3MoP0.6Oy catalysts were prepared and characterized by XRD, TPR, LRS, XPS and EPR techniques. And the catalytic performance of the catalysts for selective oxidation of propane to acrolein ...
Role of Ce on selective oxidation of propane to acrolein over Ce-Ag-Mo-P-O catalysts
(PEKING UNIV PRESS, 2003)
Role of Ce on the catalytic performance of Ce-Ag-Mo-P-O catalyst in selective oxidation of propane to acrolein was investigated. In order to establish the relationship between the catalytic performance and properties, the ...
Selective oxidation of propane to acrolein over Ce-doped Ag-Mo-P-O catalysts: influence of Ce promoter
(KLUWER ACADEMIC/PLENUM PUBL, 2003)
The selective oxidation of propane to acrolein was performed on Ce-doped Ag0.3Mo0.5P0.3Ox catalysts. The maximal acrolein yield of 4.4% with 28.7% acrolein selectivity was obtained on Ce0.1Ag0.3Mo0.5P0.3Oy catalyst. The ...
Reaction mechanism of selective oxidation of propane to acrolein over MoPO/SiO2 catalyst
(SCIENCE CHINA PRESS, 2006)
To elucidate possible reaction pathways for propane selective oxidation to acrolein over the MoPO/SiO2 catalyst, oxidative conversions of propane and possible intermediates or their probe molecules as well as the reaction ...